WebOct 1, 2010 · Silver supported on silica effectively catalyzes the aerobic side-chain oxidation of alkyl aromatic compounds under solvent-free conditions. Toluene, p-xylene, … WebResearch activities in my research group aim at linking domains of relevance in physical chemistry, chemical physics, spectroscopy and materials sciences: - polymer physics and surfaces; e ...
Enzymatic reactions towards aldehydes: An overview
WebOxidation, side-chain. The degradation of 4-nitrotoluene by Pseudomonas sp. takes place by oxidation to 4-nitrobenzoate via 4- nitrobenzyl alcohol and 4-nitrobenzaldehyde (Haigler and Spain 1993 Rhys-Williams et al. 1993 James and Williams 1998). [Pg.513] Side chain oxidation of alkylbenzenes is important in certain metabolic processes One way ... WebApr 14, 2024 · As for O atoms and O 3 molecules, the methyl group on the side chain could be removed, and the remaining structure could be further oxidized to an aldehyde group [seen in Fig. 12(d)]. In addition, the experimental double oxidation modification can also be observed, in which the side chain of Thr was oxidized to a ketone group and an aldehyde … ports macbook pro mid 2012
US20240067211A1 - Polyrotaxane and production method …
WebJan 28, 2024 · Oxidation of Alkyl Side-Chains The benzylic hydrogens of alkyl substituents on a benzene ring are activated toward free radical attack, as noted earlier. Furthermore, S N 1 S N 2 and E1 reactions of benzylic halides, show enhanced reactivity, due to the … WebReaction of Side Chains of Aromatic Compounds: 1) Alkyl Side Chain Oxidation 2) Clemmensen Reduction 3) Nitro Reduction and Amino Diazotization Alkyl Side Chain … WebMoreover, KuQ is also able to oxidize aromatic organosulfur compounds, as dibenzothiophene and 4,6-dimethyldibenzothiophene, whose oxidation is interesting in the field of fuel desulfurization. In addition, the mono-oxidation of thianthrene-5-oxide, an efficient reagent for valuable organic transformations, was achieved in 4.5 h with 5% KuQ. ports needed for splunk